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Thin films of In2O3 by atomic layer deposition using In(acac)3

Identifieur interne : 004908 ( Main/Repository ); précédent : 004907; suivant : 004909

Thin films of In2O3 by atomic layer deposition using In(acac)3

Auteurs : RBID : Pascal:09-0441229

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Abstract

Thin films of indium oxide have been deposited using the atomic layer deposition (ALD) technique using In (acac)3 (acac = acetylacetonate, pentane-2,4-dione) and either H2O or 03 as precursors. Successful growth using In(acac)3 is contradictory to what has been reported previously in the literature [J.W. Elam, A.B.F. Martinson, M.J. Pellin, J.T. Hupp, Chem. Mater. 18 (2006) 3571.]. Investigation of the dependence of temperature on the deposition shows windows where the growth rates are relatively unaffected by temperature in the ranges 165-200 °C for In(acac)3 and H2O, 165-225 °C for In(acac)3 and 03. The growth rates obtained are of the order 20 pm/cycle for In(acac)3 and H2O,12 pm/cycle for In(acac)3.

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Pascal:09-0441229

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<title xml:lang="en" level="a">Thin films of In
<sub>2</sub>
O
<sub>3</sub>
by atomic layer deposition using In(acac)
<sub>3</sub>
</title>
<author>
<name sortKey="Nilsen, O" uniqKey="Nilsen O">O. Nilsen</name>
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<s1>Centre for Materials Science and Nanotechnology (SMN), Department of Chemistry University of Oslo, P.B. 1033 Blindern</s1>
<s2>Oslo 0315</s2>
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<sZ>1 aut.</sZ>
<sZ>5 aut.</sZ>
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<name sortKey="Balasundaraprabhu, R" uniqKey="Balasundaraprabhu R">R. Balasundaraprabhu</name>
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<s1>Centre for Materials Science and Nanotechnology (SMN), Department of Physics, University of Oslo, P.B. 1048, Blindem</s1>
<s2>Oslo 0316</s2>
<s3>NOR</s3>
<sZ>2 aut.</sZ>
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<name sortKey="Monakhov, E V" uniqKey="Monakhov E">E. V. Monakhov</name>
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<s1>Centre for Materials Science and Nanotechnology (SMN), Department of Physics, University of Oslo, P.B. 1048, Blindem</s1>
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<name sortKey="Muthulcumarasamy, N" uniqKey="Muthulcumarasamy N">N. Muthulcumarasamy</name>
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<s1>Department of Physics, Coimbatore Institute of Technology</s1>
<s2>Coimbatore</s2>
<s3>IND</s3>
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<s1>Centre for Materials Science and Nanotechnology (SMN), Department of Chemistry University of Oslo, P.B. 1033 Blindern</s1>
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<s3>NOR</s3>
<sZ>1 aut.</sZ>
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<name sortKey="Svensson, B G" uniqKey="Svensson B">B. G. Svensson</name>
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<s1>Centre for Materials Science and Nanotechnology (SMN), Department of Physics, University of Oslo, P.B. 1048, Blindem</s1>
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<sZ>2 aut.</sZ>
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<idno type="ISSN">0040-6090</idno>
<title level="j" type="abbreviated">Thin solid films</title>
<title level="j" type="main">Thin solid films</title>
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<keywords scheme="KwdEn" xml:lang="en">
<term>Atomic layer method</term>
<term>Crystal growth from vapors</term>
<term>Growth mechanism</term>
<term>Growth rate</term>
<term>Indium oxide</term>
<term>Precursor</term>
<term>Temperature dependence</term>
<term>Thin films</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr">
<term>Couche mince</term>
<term>Méthode couche atomique</term>
<term>Croissance cristalline en phase vapeur</term>
<term>Précurseur</term>
<term>Mécanisme croissance</term>
<term>Dépendance température</term>
<term>Taux croissance</term>
<term>Oxyde d'indium</term>
<term>In2O3</term>
<term>8115K</term>
<term>6855A</term>
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<front>
<div type="abstract" xml:lang="en">Thin films of indium oxide have been deposited using the atomic layer deposition (ALD) technique using In (acac)
<sub>3</sub>
(acac = acetylacetonate, pentane-2,4-dione) and either H
<sub>2</sub>
O or 0
<sub>3</sub>
as precursors. Successful growth using In(acac)
<sub>3</sub>
is contradictory to what has been reported previously in the literature [J.W. Elam, A.B.F. Martinson, M.J. Pellin, J.T. Hupp, Chem. Mater. 18 (2006) 3571.]. Investigation of the dependence of temperature on the deposition shows windows where the growth rates are relatively unaffected by temperature in the ranges 165-200 °C for In(acac)
<sub>3</sub>
and H
<sub>2</sub>
O, 165-225 °C for In(acac)
<sub>3</sub>
and 0
<sub>3</sub>
. The growth rates obtained are of the order 20 pm/cycle for In(acac)
<sub>3</sub>
and H
<sub>2</sub>
O,12 pm/cycle for In(acac)
<sub>3</sub>
.</div>
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<s1>Thin films of In
<sub>2</sub>
O
<sub>3</sub>
by atomic layer deposition using In(acac)
<sub>3</sub>
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<s1>Proceedings on the Sixth Symposium on Thin Films for Large Area Electronics</s1>
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<s1>NILSEN (O.)</s1>
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<s1>BALASUNDARAPRABHU (R.)</s1>
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<s9>ed.</s9>
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<s1>ROCA I CABARROCAS (Pere)</s1>
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<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
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<s3>IND</s3>
<sZ>4 aut.</sZ>
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<s1>Utrecht University, Faculty of Science, Department of Physics and Astronomy, Debye Institute for Nanomaterials Science, Section Nanophotonics, P.O. Box 80.000</s1>
<s2>3508 TA Utrecht</s2>
<s3>NLD</s3>
<sZ>1 aut.</sZ>
</fA15>
<fA15 i1="02">
<s1>Laboratoire de Physique des Interfaces et des Couches Minces, Ecole Polytechnique</s1>
<s2>91128 Palaiseau</s2>
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<sZ>2 aut.</sZ>
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<s1>© 2009 INIST-CNRS. All rights reserved.</s1>
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<s0>Thin solid films</s0>
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<fA66 i1="01">
<s0>CHE</s0>
</fA66>
<fC01 i1="01" l="ENG">
<s0>Thin films of indium oxide have been deposited using the atomic layer deposition (ALD) technique using In (acac)
<sub>3</sub>
(acac = acetylacetonate, pentane-2,4-dione) and either H
<sub>2</sub>
O or 0
<sub>3</sub>
as precursors. Successful growth using In(acac)
<sub>3</sub>
is contradictory to what has been reported previously in the literature [J.W. Elam, A.B.F. Martinson, M.J. Pellin, J.T. Hupp, Chem. Mater. 18 (2006) 3571.]. Investigation of the dependence of temperature on the deposition shows windows where the growth rates are relatively unaffected by temperature in the ranges 165-200 °C for In(acac)
<sub>3</sub>
and H
<sub>2</sub>
O, 165-225 °C for In(acac)
<sub>3</sub>
and 0
<sub>3</sub>
. The growth rates obtained are of the order 20 pm/cycle for In(acac)
<sub>3</sub>
and H
<sub>2</sub>
O,12 pm/cycle for In(acac)
<sub>3</sub>
.</s0>
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<s0>001B80A15K</s0>
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<s0>Couche mince</s0>
<s5>01</s5>
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<s0>Thin films</s0>
<s5>01</s5>
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<s0>Méthode couche atomique</s0>
<s5>02</s5>
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<s0>Atomic layer method</s0>
<s5>02</s5>
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<s5>03</s5>
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<s0>Crystal growth from vapors</s0>
<s5>03</s5>
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<s0>Précurseur</s0>
<s5>04</s5>
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<fC03 i1="04" i2="3" l="ENG">
<s0>Precursor</s0>
<s5>04</s5>
</fC03>
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<s0>Mécanisme croissance</s0>
<s5>05</s5>
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<s0>Growth mechanism</s0>
<s5>05</s5>
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<s0>Mecanismo crecimiento</s0>
<s5>05</s5>
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<s5>06</s5>
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<s0>Temperature dependence</s0>
<s5>06</s5>
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<s0>Taux croissance</s0>
<s5>07</s5>
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<s0>Growth rate</s0>
<s5>07</s5>
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<s0>Oxyde d'indium</s0>
<s5>15</s5>
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<fC03 i1="08" i2="X" l="ENG">
<s0>Indium oxide</s0>
<s5>15</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA">
<s0>Indio óxido</s0>
<s5>15</s5>
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<fC03 i1="09" i2="3" l="FRE">
<s0>In2O3</s0>
<s4>INC</s4>
<s5>46</s5>
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<s0>8115K</s0>
<s4>INC</s4>
<s5>71</s5>
</fC03>
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<s0>6855A</s0>
<s4>INC</s4>
<s5>72</s5>
</fC03>
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<s1>320</s1>
</fN21>
<fN44 i1="01">
<s1>OTO</s1>
</fN44>
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<s1>OTO</s1>
</fN82>
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<pR>
<fA30 i1="01" i2="1" l="ENG">
<s1>E-MRS 2008 Spring Meeting. Symposium on Thin Films for Large Area Electronics.</s1>
<s3>Strasbourg FRA</s3>
<s4>2008-05-26</s4>
</fA30>
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